Paper on microwave synthesis accepted by European Journal of Inorganic Chemistry

Microwave Synthesis of Alkali-Free Hexaniobate, Decaniobate, and Hexatantalate Polyoxometalate Ions
in Eur. J. Inorg. Chem.201935, 3913-3918.   Link
M. A. Rambaran, M. Pascual-Borràs and C. A. Ohlin

Abstract:
 Microwave synthesis of polyoxoniobates and -tantalates circumvents the prolonged heating required by conventional hydrothermal methods, while providing comparable or greater yields. Microwave irradiation allows synthesis of polyoxoniobates from anhydrous niobium pentoxide, in lieu of niobic acid and sets the precedent for the discovery of new polyoxoniobates and -tantalates.

Sapphire-supported water films: Paper with PNNL collaborators just accepted in JCIS

In collaboration with Hongfei Wang (Fudan University) and other current and former Pacific Northwest National Laboratory scientists, we used Sum Frequency Generation Vibrational Spectroscopy (SFG-VS) and molecular model to provide new insight on the orientation and hydrogen bond populations of nanometric water films on sapphire (alpha-Al2O3) surfaces:

J.-F. Boily*, L. Fu., A. Tuladhar, Z. Lu, Z.M., Legg B., Wang, H.-F. Wang (2019). Hydrogen Bonding and Molecular Orientations Across Thin Water Films on Sapphire. J. Colloid Interface Sci. (accepted)

 

 

 

Clays, New Perspectives, Challenges & Opportunities workshop at MIT

Michae Holmboe gave an invited talk on the characterization of clay microstructure and molecular dynamics simulations – at the workshop “Clays, New Perspectives, Challenges & Opportunities”, May 2-3 2019, hosted by Prof Andrew Whittle and his postdoc Ali Seiphoori at the Massachusetts Institute of Technology (MIT). Read more here: clays.mit.edu

PDF/XRD/EXAFS/NMR/FTIR paper on phosphate binding on aluminum hydroxide

A multi-institution collaboration involving University of Wyoming, Argonne National Laboratory, Canadian Light Source, Stony Brook University and Huazhong Agricultural University.

“Phosphate Sorption Speciation and Precipitation Mechanisms on
Amorphous Aluminum Hydroxide” will soon be coming out in the Open Access Journal Soil Systems

Authors: Xiaoming Wang, Brian L. Phillips, Jean-François Boily, Yongfeng Hu, Zhen Hu, Peng Yang, Xionghan Feng, Wenqian Xu, Mengqiang Zhu *